Mix together the spices salt, pepper, garlic and onion powders, and paprika (optional). Divide mixture in half and season the chicken breast on both sides. Using a sharp knife to cut a slice through the middle of the chicken breast, but not all the way through, creating a pocket for the broccoli and cheese filling.
Place the broccoli in a microwaveable dish and add about 2 tablespoons of water. Cover with plastic wrap and microwave for 1 minute. Drain the excess water. Using the same dish add the bell pepper, cheese, mayo, and the remaining seasoning mixture between the chicken breast. A toothpick usually help to secure the filling in the chicken breast.
Heat a large cast iron skillet (or any skillet that you prefer and transfer to an oven safe baking dish) over medium heat, add the 1 tablespoon of olive oil. Sear the chicken for 3 to 4 minutes on each side. After searing cover the skillet with foil and bake in the preheated oven for 15 to 17 minutes, or until chicken reads 165*F. Set aside and let rest for 5 minutes.
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